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26/8/2022· The effect of this greater reactivity is that methylbenzene will react with fuming sulfuric acid at 0 C, and with concentrated sulfuric acid if they are heated under reflux for about 5 …
: 5The electronic surroundings of the middle methyl group in 1,2,3-trimethylbenzene is more compact to the outer and the methyl groups of toluene and o -xylene (see Table 4 ). Increased …
Methyl substitution effects on aromatic and methyl proton chemical shifts in several mono-, di-, and trimethyl benzenes are studied. A new method for obtaining the changes in the ring proton chemical shifts from those of methyl proton shifts at the corresponding positions is used.
Methyl substitution effects on aromatic and methyl proton chemical shifts in several mono-, di-, and trimethyl benzenes are studied. A new method for obtaining the changes in the
Methyl substitution effects on aromatic and methyl proton chemical shifts in several mono-, di-, and trimethyl benzenes are studied. A new method for obtaining the changes in the ring proton chemical shifts from those of methyl proton shifts at the corresponding positions is used.
Ingestion of benzene can cause vomiting, tachycardia, ataxia, somnolence, loss of consciousness, delirium, chemical pneumonitis with initial excitatory symptoms followed by abrupt CNS and respiratory depression. Transverse myelitis has been reported following occupational exposure. Dermal exposure can cause burns and systemic toxicity.
Although EHT was in qualitative agreement with the experiments, it overestimated the effect of the methyl groups on binding energy for xylenes and mesitylene. EHT was incorrect in predicting the direction of charge transfer, a consequence of the underestimation of the benzene π-π* energy gap by EHT.
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short-term exposure to the methyl derivatives of benzene (toluene, ortho-xylene) results in adaptive changes in the liver to their toxic effects such as an increase of the relative liver weight, proliferation of ser of hepatocytes, increased concentration of cytochrome p-450 and b-5, and increased activity of the mfo system (ungváry et al. 1976, …
short-term exposure to the methyl derivatives of benzene (toluene, ortho-xylene) results in adaptive changes in the liver to their toxic effects such as an increase of the relative liver …
None of the solvents proved to be teratogenic, the incidence of malformations did not change as a result of exposure, though an increase in skeletal anomalies (extra ribs, fused sternebrae) was …
1/9/2016· Over the years, MTBE has resulted in pollution by entering groundwater via accidental spills during manufacture, distribution and storage of blended fuel, especially through leaking underground (fuel) storage tanks (Deeb et al., 2003), in California and many other regions in …
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