Methyl Ethyl Ketone
CAS：78-93-3
Cyclohexanone
CAS：108-94-1
Acetone
CAS：67-64-1
Acetic Acid
CAS：64-19-7
Ethyl Acetate
CAS：141-78-6
Toluene
CAS：108-88-3
Benzene
CAS：71-43-2
Ethanol
CAS：64-17-5
Methanol
CAS：67-56-1
cyclohexanone monooxygenase
cyclohexanone monooxygenase(EC 1.14.13.22) - Creative Enzymes
14/1/2013· cyclohexanone monooxygenase No. EXWM-0822 Description A flavoprotein (FAD). In the alytic mechanism of this enzyme, the nucleophilic species that attacks the carbonyl group is a peroxyflavin intermediate that is generated by reaction of the enzyme-bound flavin cofactor with NAD (P)H and oxygen.
New Bioorganic Reagents: Evolved Cyclohexanone Monooxygenase …
Four mutants of the cyclohexanone monooxygenase (CHMO) evolved as alysts for Baeyer−Villiger oxidation of 4-hydroxycyclohexanone were investigated as alysts for a variety of 4-substituted and 4,4-disubstituted cyclohexanones. Several excellent alytic matches (mutant/substrate) were identified.
Crystal Structures of Cyclohexanone Monooxygenase Reveal …
Cyclohexanone monooxygenase (CHMO) is a flavoprotein that carries out the archetypical Baeyer−Villiger oxidation of a variety of cyclic ketones into lactones. Using NADPH and O 2 as …
Novel cyclohexane monooxygenase from Acidovorax sp. CHX100
Transposon mutagenesis of Acidovorax sp. CHX100 revealed a novel cytochrome P450 monooxygenase (CYP450chx) which alyzed the transformation of cyclohexane to …
シクロヘキサノンモノオキシゲナーゼ - Wikipedia
シクロヘキサノンモノオキシゲナーゼ （cyclohexanone monooxygenase）は、 カプロラクタム のつで、の である。 シクロヘキサノン + NADPH + H + + O ヘキサノ-6-ラクトン + NADP + + H O このの は シクロヘキサノン 、 、 と で、は ヘキサノ-6-ラクトン 、NADP である。 として をいる。 で、にcyclohexanone 1,2 …
Characterization and Crystal Structure of a Robust Cyclohexanone Monooxygenase …
12/12/2016· Cyclohexanone monooxygenase (CHMO; EC 1.14.13.22) is an FAD‐ and NADPH‐dependent Baeyer–Villiger monooxygenase (BVMO). 1 A wide variety of ketones are converted by CHMO into esters or lactones through the insertion of an oxygen atom on one side or the other of the carbonyl group.
Information on EC 1.14.13.22 - cyclohexanone monooxygenase
14/1/2013· 1.14.13.22 cyclohexanone monooxygenase IUB Comments A flavoprotein (FAD). In the alytic mechanism of this enzyme, the nucleophilic species that attacks the carbonyl group is a peroxyflavin intermediate that is generated by reaction of the enzyme-bound flavin cofactor with NAD (P)H and oxygen .
CMO - Cyclohexanone monooxygenase
CMO - Cyclohexanone monooxygenase PCR Polymerase Chain Reaction ODS Ozone Depleting Substances CK Creatine Kinase tRNA Transfer RNA XO Xanthine Oxidase IL Interleukin PAGE Polyacrylamide Gel Electrophoresis rRNA Ribosomal RNA SR EHS
cyclohexanone monooxygenase, cyclohexanone monooxygenase …
cyclohexanone monooxygenase:…,cyclohexanone monooxygenase,cyclohexanone monooxygenase,,,。
CN105695425A - Cyclohexanone monooxygenase and …
The invention provides appliion of a cyclohexanone monooxygenase characterized by high alytic activity, high reaction yield, and environmental friendliness to asymmetric oxidation reaction to synthesize single-configuration prazole drugs. The invention also
CMO - Cyclohexanone monooxygenase
CMO - Cyclohexanone monooxygenase PCR Polymerase Chain Reaction ODS Ozone Depleting Substances CK Creatine Kinase tRNA Transfer RNA XO Xanthine Oxidase IL Interleukin PAGE Polyacrylamide Gel Electrophoresis rRNA Ribosomal RNA SR EHS
Photoinduced Promiscuity of Cyclohexanone Monooxygenase for …
16/11/2022· The photoinduced reductive dehalogenation promiscuity of cyclohexanone monooxygenase (CHMO) with a novel mechanism of ET/PT distinct from the photoinduced promiscuity of natural reductases is reported. Various highly enantioenriched α …
シクロヘキサノンモノオキシゲナーゼ - Wikipedia
シクロヘキサノンモノオキシゲナーゼ （cyclohexanone monooxygenase）は、 カプロラクタム のつで、の である。. このの は シクロヘキサノン …
Photoinduced Promiscuity of Cyclohexanone Monooxygenase for …
Herein, we report a promiscuous cyclohexanone monooxygenase (CHMO) for the photoinduced synthesis of chiral α-fluoroketones via enantioselective reductive dehalogenation …
Large scale production of cyclohexanone monooxygenase from
1/2/2001· The cyclohexanone monooxygenase (CHMO) from Acinetobacter calcoaceticus NCI 9871 has been cloned into Escherichia coli in an L-arabinose inducible vector. The …
New Bioorganic Reagents: Evolved Cyclohexanone Monooxygenase …
Four mutants of the cyclohexanone monooxygenase (CHMO) evolved as alysts for Baeyer−Villiger oxidation of 4-hydroxycyclohexanone were investigated as alysts for a variety of 4-substituted and 4,4-disubstituted cyclohexanones. Several excellent alytic matches (mutant/substrate) were identified.
ENZYME - 1.14.13.22 cyclohexanone monooxygenase
14/1/2013· ENZYME entry: EC 1.14.13.22. cyclohexanone monooxygenase. cyclohexanone:NADPH:oxygen oxidoreductase (6-hydroxylating, 1,2- lactonizing). cyclohexanone 1,2-monooxygenase. cyclohexanone oxygenase. cyclohexanone + H (+) + NADPH + O2 <=> H2O + hexano-6-lactone + NADP (+) In the alytic mechanism of this enzyme, the …
cyclohexanone monooxygenase, cyclohexanone monooxygenase …
cyclohexanone monooxygenase:…,cyclohexanone monooxygenase,cyclohexanone monooxygenase,,,。
Cyclohexanone Monooxygenase, - Creative Biogene
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Structural Analysis of a Novel Cyclohexylamine Oxidase …
structures of cyclohexanone monooxygenase reveal complex domain movements and a sliding cofactor. J Am Chem Soc 131: 8848–8854. 20. Yachnin BJ, Sprules T, McEvoy , Lau PC, Berghuis AM (2012) The substrate-bound crystal structure of a Baeyer
Cyclohexanone Monooxygenase = 12U/mL, ammonium sulfate …
14/1/2013· Purified cyclohexanone monooxygenase has a molecular weight of 59,000 Da. It is a versatile oxygenation alyst. The enzyme uses the bound FAD-4a-OOH oxygenating intermediate to initiate transfer of oxygen to electrophilic substrate sites. The reaction consequently yields the corresponding sulfoxide and selenoxide products.
Cyclohexanone monooxygenase Semantic Scholar
Crystal structures of cyclohexanone monooxygenase reveal complex domain movements and a sliding cofactor. I. Mirza, B. Yachnin, +7 authors A. Berghuis Journal of the American Chemical Society 2009 Corpus ID: 207138937
Structural Analysis of a Novel Cyclohexylamine Oxidase …
structures of cyclohexanone monooxygenase reveal complex domain movements and a sliding cofactor. J Am Chem Soc 131: 8848–8854. 20. Yachnin BJ, Sprules T, McEvoy , Lau PC, Berghuis AM (2012) The substrate-bound crystal structure of a Baeyer
P12015 - UniProt
23/1/2007· Cyclohexanone 1,2-monooxygenase EC nuer EC:1.14.13.22 ( UniProtKB ENZYME Rhea) Organism names Organism Acinetobacter sp Taxonomic identifier 472 NCBI Taxonomic lineage Bacteria > Proteobacteria > Gammaproteobacteria > Moraxellales > Moraxellaceae > Acinetobacter Accessions Primary accession P12015 Phenotypes & Variants …
Cyclohexanone Monooxygenase = 12U/mL, ammonium sulfate …
14/1/2013· Cyclohexanone monooxygenase has been used in a study that cloned and overexpressed the 2-oxo-Δ(3)-4,5,5-trimethylcyclopentenylacetyl-CoA monooxygenase …
Tuning a bi-enzymatic cascade reaction in Escherichia coli to …
22/4/2021· Cyclohexanol is enzymatically converted into cyclohexanone by alcohol dehydrogenase (ADH) with NADPH generation, which is oxidized into ε-caprolactone by cyclohexanone monooxygenase (CHMO) with NADPH consumption. b Expression vector constructions to regulate the protein expression through RBS sequence replacements Full size …
CN105695425A - Cyclohexanone monooxygenase and …
The invention provides appliion of a cyclohexanone monooxygenase characterized by high alytic activity, high reaction yield, and environmental friendliness to asymmetric oxidation reaction to synthesize single-configuration prazole drugs. The invention also
Cyclohexanone monooxygenase - Big Chemical Encyclopedia
Cyclohexanone monooxygenase The product (6 hexanohde) is a cyclic ester or lactone (Section 19 15) Like the Baeyer-Vilhger oxidation an oxygen atom is inserted between the carbonyl group and a carbon attached to it But peroxy acids are not involved m any way the oxidation of cyclohexanone is alyzed by an enzyme called cyclohexanone …
Cyclohexanone Monooxygenase, - Creative Biogene
Home Microbial Basic Research Microbial Cell-surface Display Service Eli Surface Display Service L. lactis Surface Display Service Yeast Cell-Surface Display Service P. pastoris Surface Display Service S. cerevisiae Surface Display Service Bacillus subtilis Surface Display Service
Production of cyclohexanone monooxygenase from Acinetobacter calcoaceticus for large scale Baeyer–Villiger monooxygenase reactions - SpringerLink
Abstract Cyclohexanone monooxygenase was produced from Acinetobacter calcoaceticus grown on a medium containing both glutamate (30 g l −1) and cyclohexanol (1 g l −1 ). Productivity was increased to 650 U l −1, an order of magnitude greater than previous production methods, thereby enhancing the potential commercial utility of this enzyme.
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